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71.
Two Mississippi Valley-type (MVT) ore deposits, Kicking Horse and Monarch, have been studied with the aim of comparing the ores at the two localities and to characterize the origin of the mineralizing fluids and the ore formation process(es). Both deposits are hosted by the Middle Cambrian Cathedral Formation carbonate host rocks, Kicking Horse on the north and Monarch on the south flank of the Kicking Horse valley near Field (SE British Columbia). The ore bodies are situated at the transition of (western) basinal to (eastern) shallow-water strata of the paleo-Pacific passive margin succession in the Cordilleran Foreland Province of the Western Canada Sedimentary Basin. Both deposits are related spatially to normal faults. In both localities, the ore minerals are dominated by pyrite, sphalerite, and galena. Dolomite, minor quartz, and calcite are also present in close association with the ores. The salinity (21–30 wt% NaCl eq.) and homogenization temperatures (63–182°C) measured in fluid inclusions in carbonate, quartz, and sphalerite lie within the typical range of MVT fluid conditions. The good stoichiometry (50–53 mol% CaCO3), low δ18O values (−21 to −14‰ Vienna Peedee belemnite) and relatively high homogenization temperatures (>95°C) of the dolomite suggest the dolomites were formed under burial diagenesis. The ore-forming fluids probably interacted with siliciclastic units, based on elevated Li contents and 87Sr/86Sr ratios, which are highest in the dolomite type after the main ore stage. We propose that the ores formed from the mixing of a downward-infiltrating, sulfur-bearing halite-dissolution fluid with an upward-migrating, metal-rich evaporated seawater fluid, which had already undergone minor mixing with a dilute fluid.  相似文献   
72.
Worldwide alkali olivine basalts (AOB) and their differentiation series have been subdivided into continental, oceanic, or island-arc assemblages according to the inferred crustal environment at their time and place of eruption. No systematic differences have been found in major element composition of the AOB's from these three different environments. As plotted on (Na2O + K2O) vs. SiO2 and AMF diagrams, AOB differentiation trends also show no differences between environments. Thus, AOB appears to be a primary magma generated at sufficient depth in the mantle that its major element content is unaffected by chemical or thermal differences between mantle regions underlying continents, ocean basins, or island arcs. The major element chemistry of AOB is also apparently unaffected by passage through different types of crust.  相似文献   
73.
Predicting sediment flux from fold and thrust belts   总被引:8,自引:1,他引:8  
The rate of sediment influx to a basin exerts a first-order control on stratal architecture. Despite its importance, however, little is known about how sediment flux varies as a function of morphotectonic processes in the source terrain, such as fold and thrust growth, variations in bedrock lithology, drainage pattern changes and temporary sediment storage in intermontane basins. In this study, these factors are explored with a mathematical model of topographic evolution which couples fluvial erosion with fold and thrust kinematics. The model is calibrated by comparing predicted topographic relief with relief measured from a DEM of the Central Zagros Mountains fold belt. The sediment-flux curve produced by the Zagros fold belt simulation shows a delay between the onset of uplift and the ensuing sediment flux response. This delay is a combination of the natural response time of the geomorphic system and a time lag associated with filling, and then subsequently uplifting and re-eroding, the proximal part of the basin. Because deformation typically propagates toward the foreland, the latter time lag may be common to many ancient foreland basins. Model results further suggest that the response time of the bedrock fluvial system is a function of rock resistance, of the width of the region subject to uplift and erosion, and, assuming a nonlinear dependence of fluvial erosion upon channel gradient, of uplift rate. The geomorphic response time for the calibrated Zagros model is on the order of a few million years, which is commensurate with, or somewhat larger than, typical recurrence intervals for episodes of thrusting. However, model experiments also highlight the potential for significant variations in both geomorphic response time and in sediment flux as a function of varying rock resistance. Given a reasonable erodibility contrast between resistant and erodible lithologies, model sediment flux curves show significant sediment flux variations that are related solely to changes in rock resistance as the outcrop pattern changes. An additional control on sediment flux to a basin is drainage diversion in response to folding or thrusting, which can produce major shifts in the location and magnitude of sediment source points. Finally, these models illustrate the potential for a significant mismatch between tectonic events and sediment influx to a basin in cases where sediment is temporarily ponded in an intermontane basin and later remobilized.  相似文献   
74.
Chromium ore was treated to produce ferrochromium from 1979 until 2000 in a smelter in Burrel, 35 km NE of Tirana (Albania). As a consequence, large amounts of solid waste, i.e. slags (about 9.106 m3) have been disposed next to the smelter, disfiguring the landscape. In an attempt to define contaminated sites, heavy metal content of the different sampling media have been compared with respective background samples.In the study area, the determination of background values in soil samples is complicated due to the different geological substrates. Cr and Ni background concentrations in serpentinite-derived soils, west of the smelting plant, are markedly higher than in the Pliocene gravel/sandy soils, where the smelter is situated (Cr 2147 and 193 mg/kg, respectively; Ni 2356 and 264 mg/kg). These values are clearly lower than those encountered around the smelter. Average total Cr and Ni concentrations in soils around the smelter are 3117 and 1243 mg/kg, respectively. The highest concentrations of Cr (up to 2.3 wt.%), were recorded in samples taken near the smelting compartment within the industrial plant and next to the slags clearly indicating that the smelter forms a point source of Cr contamination. The Cr / Fe ratio is the best indicator to differentiate non-polluted (Cr / Fe Serpentinite soil: 130–390; Pliocene soils: < 130) from polluted areas (> 390 smelting nearby of the slags).Cr and Ni values for local backgrounds in stream and overbank sediments were taken in the Mat river 6 km upstream and to the east of the smelter (268 and 430 mg/kg for Cr, and 306 and 604 mg/kg for Ni, respectively). Equivalent sediments taken from the Zalli i Germanit river, which drains the smelter area are respectively 816 and 1126 mg/kg for Cr and 1115 and 1185 mg/kg for Ni.Dust samples, taken from the lofts of houses up to 2 km from the smelter, display high concentrations of Cr, Ni and Zn (average contents of 2899, 436 and 902 mg/kg, respectively). The later concentrations in the dust samples have been confirmed by mineralogical analysis where Cr-bearing mineral phases such as ferrochromium and chromium oxides, clearly relate to the activity of the smelter. Consequently, atmospheric deposition of dust particles forms a serious problem and can also be responsible for the elevated contents encountered in soil samples around the smelter.All these data show that the degree of contamination caused by industrial activity of the Burrel Cr-smelter is severe, although no Cr(VI) was detected in soil water extractions nor in the surface or groundwater where concentrations were < 0.01 mg/kg.  相似文献   
75.
This study presents a new approach to geobarometry by combining fluid inclusion and clumped isotope (Δ47) thermometry on carbonate minerals. The offset between homogenisation temperatures of primary fluid inclusions with known composition and Δ47 temperatures of the host mineral allows a direct estimation of the fluid pressure at the time of carbonate crystallisation. This new approach is illustrated via hydrothermal dolomite samples from the Variscan foreland fold‐and‐thrust belt in northern Spain. Clumped isotope analyses yield crystallisation temperatures (107–168°C) which are higher than homogenisation temperatures in corresponding samples (95–145°C). The calculated pressure values suggest that dolomitizing fluids were overpressured during formation of zebra dolomite textures, whereas lower pressures are obtained for dolomite cement from breccia textures. This new approach to geobarometry opens up the possibility of estimating the pressure of carbonate crystallisation and has potential applications in diagenesis, basin analysis, ore geology and tectonics.  相似文献   
76.
Carbonate reservoirs in the Córdoba petroleum system (NE Mexico) passed through a multiphase deformation history complicating the petroleum geology. The area evolved from passive margin and foreland setting to Laramide fold and thrust belt (FTB) that was subsequently buried below the Tertiary-Quaternary Veracruz Basin, which in turn underwent transpressional deformation. Reconstruction of paleo-burial (erosion) and paleo-thermicity through the different zones of the FTB and adjacent foreland is a challenging task since classical calibration tools fail to discriminate between several kinematic and thermal models. In this study results from detailed diagenetic and fluid inclusion (FI) analyses on carbonates from the western part of the Córdoba Platform helped constraining paleo-thermicity. Combined microthermometry, synchrotron FTIR analyses and PVT modeling of cogenetic hydrocarbon-aqueous FI allowed also calculation of absolute pressures. Thermal modeling exercises calibrated with organic maturity parameters, bottom-hole temperatures or temperatures from FI demonstrate that without controlling also paleo-erosion the model results may be misleading.  相似文献   
77.
Coastal and island states of the Western Indian Ocean lack scientific and management capacity to draw sustainable benefits from their Exclusive Economic Zones. Declining ecosystem services and unregulated fishing has prompted nine riparian countries to develop a regional framework for capacity building and scientific development towards collective management of shared resources. Supported by the Global Environment Facility (GEF), the Agulhas and Somali Currents large marine ecosystems programme consists of three inter-related modules, supported by different agencies: land-based impacts on the marine environment (UNEP); productivity, ecosystem health and nearshore fisheries (UNDP) and transboundary shared and migrating fisheries resources (World Bank). The latter is the South Western Indian Ocean Fisheries Project (SWIOFP), a 5-year joint data gathering and fisheries assessment initiative. SWIOFP is a prelude to long-term cooperative fisheries management in partnership with the newly established FAO–South Western Indian Ocean Fisheries Commission (SWIOFC). We describe the development of SWIOFP as a model of participatory regional scientific cooperation and collective ocean management.  相似文献   
78.
In the Northern Emirates, Jurassic and Lower Cretaceous platform carbonates of the Musandam parautochthonous units are tectonically overlain by siliciclastic units of the Hawasina–Sumeini allochthon, which derive from the former paleo-slope domain and a more distal basinal portion of the Arabian margin of the Tethys, respectively. All these tectonic units display numerous evidences of paleo-fluid circulations, accounting for dolomitisation and recrystallisation of the rock matrix (Musandam Platform units), as well as cementation of fractures. Polymict breccias of Upper Cretaceous Ausaq Formation which underlay the sole thrust of the Hawasina–Sumeini allochthon also record episodes of hydraulic fracturing, whereas fluid inclusion data indicate precipitation at high temperature in relation to paleo-fluid flow. Petrography of thin-sections (conventional and cathodoluminescence microscopic techniques) as well as fluid inclusion and stable isotopes analyses, were combined with micro-tectonic studies. These analytical data document (1) the paragenetic sequence of diagenetic products for the Musandam Platform (which constitutes a carbonate reservoir analogue) and Sumeini units of the Dibba Zone, as well as (2) the nature of the paleo-fluids circulating along fractures and the sole thrust of the Hawasina–Sumeini allochthon. The main results of this petrographic approach are qualitative, evidencing (1) the rapid and vertical transfer of hot fluids in the vicinity of the former slope to platform transition, accounting for episodes of hydrothermal dolomitisation, as well as (2) early (i.e. pre-orogenic) and late (i.e. post-orogenic) episodes of emersion of the carbonate units, accounting for additional interactions with meteoric fluids and karstification. In order to better link these diagenetic events with the overall burial, thermal and kinematic evolution of the Arabian margin, basin modelling with Ceres2D, including fluid flow and pore-fluid pressure modelling, was subsequently performed along a regional transect (D4) located in the vicinity of the samples localities and cross-cutting the Northern Oman Mountains from Dibba in the east up to the Arabian Gulf in the west. New subsurface constraints provided by deep seismic profiles were used to constrain the architecture of the cross-section, and to test various hypotheses on the lateral and vertical connection, timing and hydrodynamic behaviour of the faults. This Ceres basin modelling also provides new quantitative estimates of the paleo-fluid pathways, of the timing and velocities of the fluid transfers and of the evolution of pore-fluid pressures. Ultimately, this integration of petrographic studies on surface samples and coupled kinematic and fluid flow basin modelling provides an updated scenario for the succession of tectonically controlled episodes of fluid rock interactions, namely dolomitisation and karstification recorded in the Mesozoic platform carbonates of the Northern Emirates.  相似文献   
79.
This study is based on the morphosedimentary analysis of the cliff-top storm deposits accumulated on the coast of Banneg Island located in the archipelago of Molène (Brittany, France). These CTSDs comprise large, tabular clasts quarried from the upper part of the cliff and the backing scoured platform by giant oceanic storm waves impacting directly the western coast of the island. An analysis of the distribution and the geomorphology of these accumulations were carried out using the DGPS topographic surveys. Most of the clasts are organised into imbricate boulder clusters or ridges deposited between 7.5 and 14.5 masl. 52 accumulations were inventoried from the north to the south of the island, representing a global volume of 1000 m3. The median size of the clasts calculated is equivalent to 0.8 × 0.6 × 0.4 m and a weight of 0.6 t. The largest one measuring 5.3 × 3.9 × 0.5 m (≈ 32 t) is located in the centre of the island (ridge #28). It has been deposited 14 m inland from the edge of the cliff at the elevation of 9 m. Sediment analysis shows that clast sizes become smaller with increasing distance from the shoreline, but there is no relationship between the sorting and the distance inland. A study of the hydrodynamic conditions inducing clast transport was undertaken by an analysis of the wave data from the 1989 to the 1990 winter storms. Models of wave runup indicate that their highest water levels may have reached up to 19 masl, 5 to 10 m higher than the top of the cliff. Submersion by giant storm waves has been more important and frequent in the centre and the south of the island. Wave data over the 1979 to the 2007 period shows that no events as powerful as those of the 1989 to the 1990 winter were recorded during the last 30 years. Yet, it appears that the 1979–1990 decade was characterized by important morphogeneous events while the following period (1990–2007) has experienced a sharp decrease in storm events. These variations could be attributed to the inversion from a negative towards a positive phase in the North Atlantic Oscillation index.  相似文献   
80.
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